By István T. Horváth, Ferenc Joó
Within the final 15 years aqueous organometallic chemistry and catalysis has emerged from being a laboratory interest to develop into a longtime box of analysis. themes reviewed the following contain mechanistic reviews at the impact of water on catalyzed reactions, the training of water soluble phosphines as ligands for catalysis, steel catalyzed natural reactions in water (hydrogenation, hydroformylation, carbonylation, olefin metathesis, hydrophosphination, etc.), chiral ligands and enantioselective catalysis, organometallic radical photochemistry in aqueous ideas, bioorganometallic chemistry, organometallic reactions of biopolymers, and catalytic amendment of biomembranes. The precis of modern effects is supplemented by means of an overview of possible destiny learn traits.
Audience: Researchers in either academia and undefined, in addition to graduate scholars of homogeneous catalysis.
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Additional resources for Aqueous Organometallic Chemistry and Catalysis
Am Chem. Soc. (1991) 113,4008. 7. Ladipo, F. ; Merola, J. S. Inorg. Chem. (1990) 29, 4172. 8. Ladipo, F. ; Merola, J. S. Inorg. Chem. (1993) 32, 1681. ORGANOMETALLIC RADICAL CHEMISTRY IN AQUEOUS SOLUTION DAVID R. TYLER University of Oregon Department of Chemistry, Eugene, Oregon USA 97403 1. , reaction 1 . , reaction 2. In addition to their versatility, two other features make the 19electron complexes ideal choices as reducing agents for many applications. First, the complexes are easy to generate: the metal-metal bonded dimers are convenient precursors and the wavelength of irradiation (A.
Catal. 71, LI-L5 8. Larpent, C. and Patin, H. (1988) Organic chemistry in water (part ll). Nucleophilic addition of water-soluble phosphines on activated olefins, Tetrahedron 44, 6107-6118 9. I and 106, F. (1993) The effect of phosphonium salt formation on the kinetics of homogeneous hydrogenations in water utilizing a rhodium meta-sulfonatophenyl-diphenylphosphine complex, l. Mol. Catal. 84 157-163 10. W. C. (1990) Nucleophilic addition of phosphines to carbonyl groups. Isolation of I-hydroxy phosphonium and 1-(trimethylsiIoxy)phosphonium salts and the crystal structure of (l-hydroxy-l-methylethyl)-triphenylphosphonium bromide, l.
The procedure was essentially identical to that above except that didodecyldimethylammonium bromide (DDAB) was used as the surfactant and the amounts of benzene and aqueous solution were reversed. Mv+ was again detected by electronic absorption and esr spectroscopy. , K3Fe(CN)6. This complex was reduced by a procedure essentially identical to the one described above for My 2+, the only difference being that sodium dodecyl sulfate was used as the surfactant. The product of the reduction was Prussian Blue.